Atomic level understanding of the nanoscale Kirkendall effect
Atomic level understanding of the nanoscale Kirkendall effect作者机构:Department of Materials Science and EngineeringUniversity of WashingtonSeattleWA 98195-2120USA
出 版 物:《Science Bulletin》 (科学通报(英文版))
年 卷 期:2017年第62卷第12期
页 面:818-819页
核心收录:
学科分类:07[理学] 070205[理学-凝聚态物理] 0702[理学-物理学]
主 题:Kirkendall效应 纳米尺度 原子 水 金纳米粒子 扩散机制 反应条件 实时跟踪
摘 要:Exactly 70 years after Kirkendall’s revolutionary experiments established the vacancy diffusion mechanism and the resultant Kirkendall effect and Kirkendall pores[1],Sun et al.[2]advanced the understanding of the Kirkendall effect to near atomic level with the real-time tracking three-dimensional(3D)evolution of colloidal nanoparticles under real reaction conditions.Smigelskas and Kirkendall[1]in 1947 reported an experiment on the interdiffusion between copper and zinc in a