Erbium(Ⅲ) PVC membrane sensor based on N-(benzyloxycarbonyloxy)succinimide as a new neutral ionophore

作     者：Hassan Ali Zamani 

作者机构：Department of Applied ChemistryQuchan BranchIslamic Azad UniversityQuchanIran 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2011年第22卷第3期

页      面：346-349页

核心收录：

学科分类：080202[工学-机械电子工程] 08[工学] 0703[理学-化学] 0802[工学-机械工程] 

基　　金：the kind financial support provided by the Research Council of Quchan Islamic Azad University 

主　　题：Sensor Potentiometry Ion-selective electrode PVC membrane 

摘      要：In this study,a new Er^3＋ sensor based on N-（benzyloxycarbonyloxy）succinimide（BCS） as a neutral carrier has been constructed. The sensor exhibits potential linear response with a Nernstian slope of 20.5±0.4 mV/decade in the concentration range of 1.0×10^-6to 1.0×10^-2mol/L of Er^3＋.It has a very short response time（10 s）,detection limit of 6.3×10^-7 mol/L and a good selectivity relative to a wide variety of other metal ions including common alkali,alkaline earth,heavy,and transition metal *** can be used in the pH range of 2.5-10.6 without any considerable divergence in *** proposed sensor was successfully applied for the recovery of Er^3＋ ions spiked in tap and river water samples.