Correlation between the Standard Formation Enth alpy and the Path Index of Pyridine Derivatives

作     者：LI Liang chao 1 ,LIAO Gui ying 1,2 ,JIANG Sheng bin 2 ,WANG Ying xi 2 ,SUN Ju tang 3 1. Departmnt of Chemistry, Jingzhou Normal College, Jingzhou, China, 434100 2. Hubei, Research Institute of Chemistry, Wuhan, China, 430074 

作者机构：Department of Chemistry Jingzhou Normal College Jingzhou China Hubei Research Institute of Chemistry Wuhan China College of Chemistry Wuhan University Wuhan China 

出 版 物：《Wuhan University Journal of Natural Sciences》 (武汉大学学报（自然科学英文版）)

年 卷 期：2000年第5卷第2期

页      面：229-232页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：Supported by the National Natural Science Foundation of China!(29971024) 

主　　题：Key words pyridine derivatives standard formation enthalpy path index 

摘      要：A formulated as △fH m ? (PPDs,g)=a+ΣbiPi + cifi is put forward for estimating standard formation enthalpies of pyridine-derivatives (PDDs), in which,P i is path index andc i f i is an amended term of interaction between substituent and N atom on pyridine ring. The Calculations based on the model were carried out for some pyridine-derivatives. The values of standard formation enthalpy calculated are consistent with those in literature.