Synthesis of CdS/m-Ti02 Mesoporous Spheres and Their Application in Photocatalytic Degradation of Rhodamine B Under Visible Light

作     者：CUI Shu LI Xuesong LI Yanjuan ZHAO Haixin WANG Yuanyuan LI Nan LI Xiaotian LI Guodong 

作者机构：Key Laboratory of Automobile Materials Ministry of Education College of Material Science and Engineering Jilin University Changehun 130012 P. R. China School of Physics Tonghua Normal University Tonghua 134002 P R. China State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry Jilin University Changchun 130012 P. R. China 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：2017年第33卷第3期

页      面：436-441页

核心收录：

学科分类：081702[工学-化学工艺] 081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学] 

基　　金：Supported the National Natural Science Foundation of China(Nos.21076094 and 21673097) 

主　　题：Cadmium sulfide Titanium dioxide Heteroarchitecture Mesoporous material Photocatalysis Visible light 

摘      要：CdS/m-TiO2 heteroarchitecture with CdS nanocrystals loaded on mesoporous TiO2（m-TiO2） spheres was successfully synthesized via sol-gel method followed by solvothermal treatment. The material with uniform diameter of ca. 750 nm possesses regular mesoporous structure and large specific surface area of 100.5 m2/g. When used to photodegradate Rhodamine B（RB） under visible light, the CdS/m-TiO2 heteroarchitecture exhibits improved photo-catalytic performance in comparison with pure m-TiO2 or CdS. The excellent photocatalytic activity is closely related to the facilitated separation of electron-hole pairs derived from the CdS/m-TiO2 heterojunction and mesoporous structure with high specific surface area and adequately exposed active sites.