Silver-Catalyzed Cascade Radical Cyclization forStereoselective Synthesis of Exocyclic Phosphine Oxides
Silver-Catalyzed Cascade Radical Cyclization for Stereoselective Synthesis of Exocyclic Phosphine Oxides作者机构：State Key Laboratory of Applied Organic Chemistry Lanzhou University Lanzhou Gansu 730000 China State Key Laboratory for Oxo Synthesis and Selective Oxidation Lanzhou bTstitute of Chemical Physics Chinese Academy of Sciences Lanzhou Gansu 730000 China
出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)
年 卷 期：2017年第35卷第3期
页 面：316-322页
核心收录：
基 金：国家自然科学基金 国家教育部长江学者与创新团队发展计划
主 题：silver‐catalyzed cascade radical cyclization 1,6‐dienes exocyclic phosphine oxides
摘 要：A silver‐catalyzed phosphorylation/cyclization radical cascade of 1,6‐dienes has been developed. The reaction process involves in a one‐pot operation described as an autotandem catalytic process with a cascading radical cyclization for the construction of C—P and C—C bond with high stereoselectivity. Moreover, it also affords an efficient method for the synthesis of valuable exocyclic phosphine oxides compounds with broad substrate applicability, mild reaction condition and succinct reaction system.
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