Expedient copper-catalyzed borylation reactions using amino acids as ligands

作     者：Meng-Yan Liu Shi-Bin Hong Wei Zhang Wei Deng 

作者机构：Research Center of Nano Science and TechnologyShanghai University School of Chemical and EngineeringShanghai Institute of Technology 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2015年第26卷第3期

页      面：373-376页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：support from the Eastern Scholar,Shanghai Pujiang Program,Key Subject of Shanghai Municipal Education Commission,Natural Science Foundation of Shanghai (No.12ZR1410500) NSFC (Nos.21102088,51202138 and 21174081) 

主　　题：catalyzed alkyl esters boron reagent halide entries moiety aromatic cyclohexane 

摘      要：Amino acids were found to be as good ligands for copper-catalyzed borylation reactions of primary and secondary alkyl halides,and the B2pin2 acted as bi-boron source for *** high reaction efficiency and mild conditions make the new catalyst system a useful alternative to the recently developed methods for the preparation of alkylboronic esters.