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Ternary Fe3O4@PANI@Au nanocomposites as a magnetic catalyst for degradation of organic dyes

Ternary Fe_3O_4@PANI@Au nanocomposites as a magnetic catalyst for degradation of organic dyes

作     者:ZHU YuMei ZHOU XiaoWei CHEN DongSheng LI Fang XUE Tao Ahmed Saad FARAG 

作者机构:Institute of New-Energy Materials School of Materials Science and Engineering Tianjin University Tianjin 300072 China Analysis Centre Tianjin University Tianjin 300072 China Eastman Institute for Oral Health University of Rochester Medical Center Rochester NY 14620 USA 

出 版 物:《Science China(Technological Sciences)》 (中国科学(技术科学英文版))

年 卷 期:2017年第60卷第5期

页      面:749-757页

核心收录:

学科分类:081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基  金:supported by the National Natural Science Foundation of China(Grant No.11272232) Science and Technology Supporting Major Project of Tianjin City(Grant No.16YFZCSY00850) 

主  题:Fe3O4@PANI@Au catalytic magnetic degradation 4-nitrophenol dyes 

摘      要:Magnetic Fe_3O_4@PANI@Au nanocomposites are fabricated through electrostatic self-assembly and seed growth *** rate constant K_(app) is calculated to be 8.63×10^(-3) s^(-1) at room temperature for the reduction of 4-nitrophenol to 4-aminophenol with an excessive amount of NaBH_4 as a model system showing outstanding catalytic efficiency and *** recyclable performance,the catalyst exhibits slight loss in catalytic performance on the conversion of 4-nitrophenol after running for more than 10 ***,the smaller and simpler the structure,the easier the molecular structure can be degraded,and the faster the cationic dyes can be degraded than the anionic dyes,which can reveal the *** practical application,Congo red as a pollutant of the lake water is degraded rapidly after Fe_3O_4@PANI@Au is added to the solution in a few *** has been demonstrated that magnetic Fe_3O_4@PANI@Au nanoparticle composite is a promising catalyst for environment sewage.

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