Mesoporous Ti-Mo Mixed Oxides Catalyzed Transformation of Carbohydrates into 5-Hydroxymethylfurfural

作     者：Zhang Qiuyun Wei Fangfang Luo Dan Ma Peihua Zhang Yutao 

作者机构：School of Chemistry and Chemical Engineering Anshun University Anshun 561000 Special and Key Laboratory of Functional Materials and Resource Chemistry of Guizhou Provincial Education Department Anshun University Anshun 561000 School of Chemistry and Chemical Engineering Guizhou University Guiyang 550025 

出 版 物：《China Petroleum Processing & Petrochemical Technology》 (中国炼油与石油化工（英文版）)

年 卷 期：2017年第19卷第1期

页      面：26-32页

核心收录：

学科分类：081702[工学-化学工艺] 0808[工学-电气工程] 081705[工学-工业催化] 08[工学] 0820[工学-石油与天然气工程] 0821[工学-纺织科学与工程] 0817[工学-化学工程与技术] 0807[工学-动力工程及工程热物理] 0827[工学-核科学与技术] 0703[理学-化学] 0802[工学-机械工程] 0702[理学-物理学] 0801[工学-力学（可授工学、理学学位）] 

基　　金：financially supported by the Joint Science and Technology Funds of Guizhou Science and Technology Department of Anshun Municipal Government and the Anshun University (No. LH7694) the 2016 National Innovative Entrepreneurship Training Program for Undergraduates (No. 201510667020) 

主　　题：mesoporous catalyst solid acid heterogeneous catalysis carbohydrate 5-hydroxymentylfurfural(HMF) 

摘      要：Mesoporous Ti-Mo mixed oxides were prepared via a facile approach using stearic acid as the template, and were characterized using XRD FT-IR, nitrogen adsorption-desorption isotherm and TEM techniques. The catalytic activity of the prepared mesoporous Ti-Mo mixed oxides was first evaluated for the dehydration of fructose to 5-hydroxymethylfurfural(HMF), and a 50.3% yield of HMF was obtained within 60min at 120℃. Moreover, moderate yields of HMF could also be achieved from glucose and sucrose. The mesoporous catalyst could be simply separated from the reaction mixture after termination of the reaction and reused five times with no significant loss of catalytic activity.