Nonadiabatic collision model calculations of ion-pair formation cross sections of Cs+O2→Cs++O2-

作     者：CAI, Zheng-Ting MU, Yu-Guang DENG, Cong-HaoInstitute of Theoretical Chemistry, Shandong University, Jinan, Shandong 250100, China 

作者机构：Institute of Theoretical Chemistry Shandong University Jinan Shandong 250100 China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：1995年第13卷第3期

页      面：193-198页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学] 

基　　金：Project supported by the National Natural Science Foundation of China and the Special DoctoralFund of the Chinese Education Committee 

主　　题：Ion-pair formation reaction nonadiabatic collision model two-state potential energy surface quantum scattering theory. 

摘      要：This paper has improved Hickman s nonadiabatic collision model by substituting Hickman s constant velocity classical straight line trajectory approximation with the solution of motion equation mR=-dV(R)/dR, and has calculated the cross sections of ion-pair formation Cs+O2 -Cs++O2- with the improved nonadiabatic collision model (INCM). A comparison of our results with other theoretical and experimental results has been made.