Synthesis and Properties of a Novel 3D Europium Coordination Polymer with Helical Chain and （3,6）-Connected rtl Net

作     者：Zhifeng Liu Bowen Lai Huiliang Wen Julianne Robbins Nei Huang 

作者机构：State Key Laboratory of Food Science and Technology Nanchang University Nanchang Jiangxi 330047 China Chemicals' Analysis Department Nanchang Institute for Food and Drug Control Nanchang Jiangxi 330038 China School of Chemistry and Biochemistry Georgia Institute of Technology Atlanta Georgia 30332 United States Jiangxi Sinograin Quality Supervision Center Nanchang Jiangxi 330000 China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2016年第34卷第12期

页      面：1304-1308页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学] 

基　　金：support from the State Key Laboratory of Food Science and Technology of Nanchang University the Jiangxi Science and Technology Support Program the Bureau of Education of Jiangxi Province 

主　　题：europium coordination polymer helix topological structure luminescence magnetism 

摘      要：The first coordination polymer of 2,2＇-（（4-carboxymethyl-1,3-phenylene）bis（oxy）） diacetic acid （H3L） with eu- ropium（[II） ion, [Eu（L）（H2O）]＇3H2O （1）, has been hydrothermally synthesized and structurally characterized. Complex 1 exhibits a 3D coordination polymer with helical chain and rtl topology of the point symbol （4·6^2）2（4^2·6^10·8^3） based on [Eu2（COO）4] as secondary building unit （SBU）. Furthermore, the luminescent and magnetic properties of complex 1 are studied.