Nano-Li3V2（PO4）3/C Synthesized by Thermal Polymerization Method as Cathode Material for Lithium Ion Batteries

作     者：Bin Cheng Lian-sheng Jiao Zhong-feng Tang Sheng-jie Zhang Hong-li Chen Chun-hua Chen 

作者机构：CASKeyLaboratoryofMaterialsforEnergyConversionsDepartmentofMaterialsScienceandEngineering&CollaborativeInnovationCenterofSuzhouNanoScienceandTechnologyUniversityofScienceandTechnologyofChinaHefei230026China DepartmentofChemistryHebeiNormalUniversityforNationalitiesChengde067000China 

出 版 物：《Chinese Journal of Chemical Physics》 (化学物理学报（英文）)

年 卷 期：2016年第29卷第6期

页      面：699-702,I0001页

核心收录：

学科分类：081702[工学-化学工艺] 0808[工学-电气工程] 08[工学] 0817[工学-化学工程与技术] 

基　　金：the National Natural Science Foundation of China Hefei Center of Materials Science and Technology Education Ministry of Anhui Province 

主　　题：Lithium vanadium phosphate Thermal polymerization Nanoparticles Acrylic acid 

摘      要：A nano-Li3V2（PO4）3/C powder was successfully prepared by a thermal polymerization method. The particle sizes of the intermediate product powder and the final product Li3V2（PO4）3 are all less than 200 nm. The carbon is partially coated on the surface of Li3V2（PO4）3 particles and the rest exists between particles with a total carbon content of 4.6wt%. This nano-Li3V2（PO4）3/C sample shows a discharge capacity of 124 mAh/g with-out capacity fading after 100 cycles at 0.1 C in the voltage rang of 3.0-4.3 V. Excellent rate performance is also achieved with a capacity of 80 mAh/g at 20 C in 3.0-4.3 V and 100 mAh/g at 10 C in 3.0-4.8 V. This study suggests that the thermal polymerization method is suitable to synthesize nano-Li3V2（PO4）3/C materials.