Solvent-assisted synthesis of porous g-C_3N_4 with efficient visible-light photocatalvtic performance for NO removal

作     者：张文东 赵再望 董帆 张育新 Wendong Zhang;Zaiwang Zhao;Fan Dong;Yuxin Zhang

作者机构：重庆大学材料科学与工程学院重庆400044 重庆师范大学科研处重庆401331 重庆工商大学环境与资源学院重庆市催化与功能有机分子重点实验室重庆400067 

出 版 物：《Chinese Journal of Catalysis》 (催化学报（英文）)

年 卷 期：2017年第38卷第2期

页      面：372-378页

核心收录：

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基　　金：supported by the China Postdoctoral Science Foundation Funded Project (2016M592642) Project from Chongqing Education Commission (KJ1600305) Chongqing Basic Science and Advanced Technology Research (cstc2016jcyjAX0003) the Start-up Foundation for Doctors of Chongqing Normal University (15XLB010, 15XLB014) the National Natural Science Foundation of China (51478070, 51108487) the Innovative Research Team of Chongqing (CXTDG201602014)~~ 

主　　题：Solvent-assisted Graphitic carbon nitride Visible light Photocatalytic performance Nitrogen oxide removal 

摘      要：Graphitic carbon nitride（g-C3N4） with efficient photocatalytic activity was synthesized through thermal polymerization of thiourea with the addition of water（CN-W） or ethanol（CN-E） at 550 ℃for 2 *** physicochemical properties of the g-C3N4 were investigated by X-ray diffraction,transmission electron microscopy,ultraviolet-visible spectroscopy,photoluminescence spectroscopy,diffuse-reflection spectroscopy,BET and BJH surface area characterization,and elemental *** carbon content was found to have self-doped into the g-C3N4 matrix during the thermal polymerization of thiourea and ***-W and CN-E showed considerably enhanced visible-light photocatalytic activity,with NO removal percentages of 37.2%and 48.3%,*** with pure g-C3N4,both the short and long lifetimes of the charge carriers in CN-W and CN-E were found to be *** mechanism of improved visible-light photocatalytic activity was *** present work may provide a facile route to optimize the microstructure of g-C3N4photocatalysts for high-performance environmental and energy applications.