Modified ADM1 for modeling free ammonia inhibition in anaerobic acidogenic fermentation with high-solid sludge

作     者：Jie Bai He Liu Bo Yin Huijun Ma Xinchun Chen 

作者机构：School of Environmental and Civil EngineeringJiangnan UniversityWuxi 214122China 

出 版 物：《Journal of Environmental Sciences》 (环境科学学报（英文版）)

年 卷 期：2017年第29卷第2期

页      面：58-65页

核心收录：

学科分类：083002[工学-环境工程] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 080702[工学-热能工程] 08[工学] 0807[工学-动力工程及工程热物理] 09[农学] 0903[农学-农业资源与环境] 

基　　金：supported by the Joint Innovative R&D Program of University and Industry(No.BY2014023-03) National Key Technology R&D Program of the Ministry of Scienceand Technology(No.2014BAD24B03-02) 

主　　题：High-solid sludge ADM1 Semi-continuous Full scale Free ammonia inhibition 

摘      要：Anaerobic acidogenic fermentation with high-solid sludge is a promising method for volatile fatty acid（VFA） production to realize resource recovery. In this study, to model inhibition by free ammonia in high-solid sludge fermentation, the anaerobic digestion model No. 1（ADM1） was modified to simulate the VFA generation in batch, semicontinuous and full scale sludge. The ADM1 was operated on the platform AQUASIM *** kinds of inhibition forms, e.g., simple inhibition, Monod and non-inhibition forms,were integrated into the ADM1 and tested with the real experimental data for batch and semi-continuous fermentation, respectively. The improved particle swarm optimization technique was used for kinetic parameter estimation using the software MATLAB 7.0. In the modified ADM1, the Ksof acetate is 0.025, the km,acis 12.51, and the KI_NH3is 0.02,respectively. The results showed that the simple inhibition model could simulate the VFA generation accurately while the Monod model was the better inhibition kinetics form in semi-continuous fermentation at pH 10.0. Finally, the modified ADM1 could successfully describe the VFA generation and ammonia accumulation in a 30 m^3full-scale sludge fermentation reactor, indicating that the developed model can be applicable in high-solid sludge anaerobic fermentation.