Synthesis of nanoscale CeAl4 and its high catalytic efficiency for hydrogen storage of sodium alanate

作     者：Jian Sun Xue-Zhang Xiao Ze-Jun Zheng Xiu-Lin Fan Chen-Chen Xu Lang-Xia Liu Shou-Quan Li Li-Xin Chen 

作者机构：State Key Laboratory of Silicon MaterialsKey Laboratory of Advanced Materials and Applications for Batteries of Zhejiang ProvinceSchool of Materials Science and EngineeringZhejiang UniversityHangzhon 310027China 

出 版 物：《Rare Metals》 (稀有金属（英文版）)

年 卷 期：2017年第36卷第2期

页      面：77-85页

核心收录：

学科分类：0806[工学-冶金工程] 08[工学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 0702[理学-物理学] 

基　　金：financially supported by the National High Technology Research&Development Program of China(No.2012AA051503) the National Natural Science Foundation of China(Nos.51171173 and 51471151) the China Postdoctoral Science Foundation(No.2012M521167) the Program for Innovative Research Team in University of Ministry of Education of China(No.IRT13037) the Zhejiang Provincial Science&Technology Program of China(Nos.2014C31134 and 2015C31035) 

主　　题：Complex hydride NaAlH4 Nanoscale CeAl4 Hydrogen storage Catalytic mechanism 

摘      要：Nanoscale CeAl4 was directly synthesized by the thermal reaction between CeH2 and nano-aluminum at300℃.Then nano CeAl4-doped sodium alanate（NaAlH4）was synthesized by ball milling NaH/Al with 0.04CeAl4under hydrogen atmosphere at room temperature,and the catalytic efficiency of nanoscale CeAl4 for hydrogen storage of NaAlH4 was systematically *** is shown that CeAl4 can effectively improve the dehydrogenation properties of sodium alanate *** 0.04CeAl4-doped NaAlH4 system starts to release hydrogen below 80℃,completes dehydrogenation within 10 min at 170℃,and exhibits good cycling de/hydrogenation kinetics at relatively lower temperature（100-140℃）.Apparent activation energy of the dehydrogenation of NaAlH4 can be effectively reduced by addition of CeAl4,resulting in the decrease in desorption ***,by analyzing the reaction kinetics of nano CeAl4-doped NaAlH4sample,both of the decomposition steps are conformed to a two-dimensional phase-boundary growth *** mechanistic investigations gained here can help to understand the de-/rehydrogenation behaviors of catalyzed complex metal hydride systems.