Porphyrins and Phthalocyanines Catalyzed Direct C--H Arylation

作     者：Ching Tat To Wu Yang Kin Shing Chan 

作者机构：Department of Chemistry The Chinese University of Hong Kong Shatin New Territories Hong Kong China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2016年第34卷第10期

页      面：955-961页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：Innovation and Technology Support Programme of Hong Kong [ITS/001/12] Hong Kong PhD Fellowship 

主　　题：porphyrin phthalocyanine C--H arylation C--C coupling radical reaction 

摘      要：Catalytic direct functionalization of unreactive C--H bonds represents a sustainable and more atom economical transformation process. Porphyrin and pbthalocyanine derivatives show promising catalytic activities in direct C-- H arylation reactions. These reactions share a common C--C bond formation process via homolytic radical substi- tution. This review summarizes the catalytic direct C--H arylation reactions catalyzed by metalloporphyrins, free base porphyrins and free base phthalocyanines.