Growth and Characteristics of Nd^(3+):GdAl_3(BO_3)_4 Crystal

作     者：TU Chao-Yang② ZHU Zhao-Jie LI Jian-Fu WU Bai-Chang (Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China) BRENIER Alain (Laboratoire de Physico-Chimie des Mat閞iaux Luminescents, Universit?Claude Bernard-Lyon1,UMR CNRS 5620, France) 

作者机构：Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian 350002 China 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学（英文）)

年 卷 期：2003年第22卷第2期

页      面：169-173页

核心收录：

学科分类：07[理学] 070205[理学-凝聚态物理] 08[工学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 0702[理学-物理学] 

基　　金：Supported by the Natural Science Foundation of Fujian province (2000F007) 

主　　题：flux crystal growth Nd3+:GdAl3(BO3)4 crystal self-frequency changing laser 

摘      要：Nd3+:GdAl3(BO3)4 (NGAB) crystal with the size of 30 mm was grown from the solvent system of K2O-Gd2O3-MoO3-B2O3 by combining accelerated seed rotation technology with medium seeded solution growth (MSSG) method, and its crystal structure has been determined by X-ray powder diffraction. It crystallizes in the trigonal system, space group R32 with a = 9.2734(2), c = 7.2438(1) ? V = 538 ?, Z = 3 and Dc = 4.379 g/cm3. The absorption and emission spectra of NGAB in the function of s and polarizations at room temperature have been measured. UV generation tuneable in 378～382 nm, green (531 nm) generation and blue generation tuneable in 436～443 nm as well as red (669 nm) generation by self-frequency changing were obtained with the output of 105, 119.5, 445 and 19 mJ/pulse, respectively, when the crystal was pumped by a dye laser.