Privileged strategies for direct transformations of inert aliphatic C–H bonds

作     者：Guihua Chen Zhang-Jie Shi 

作者机构：College of Chemistry and Green Chemistry CenterPeking University 

出 版 物：《National Science Review》 (国家科学评论(英文版))

年 卷 期：2014年第1卷第2期

页      面：172-175页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：supported by the National Basic Research Program of China(2009CB825300) the National Natural Science Foundation of China(20925207,21002001 and 21332001) 

主　　题：H bonds Privileged strategies for direct transformations of inert aliphatic C 

摘      要：Functional group transformations are central to organic ***,the functionalities used in such transformations are highly active organic groups such as halogens,ester groups and hydroxyl ***–hydrogen bonds are ubiquitous structural motifs in organic compounds,but they are not considered to be functionalgroups because(1)in general,the bond dissociation energy of a C–H bond is high,and therefore,such bonds