Effect of Cadmium Substitution on Structural and Magnetic Properties of Nano Sized Nickel Ferrite
镉取代对纳米镍铁氧体结构和磁性的影响作者机构:Adarsh学院化学系:Omerga奥兰加巴德431004 Babasaheb Ambedkar Marathwada博士大学物理系奥兰加巴德431004 S.C.S学院化学系研究生部与研究中心Omerga413606
出 版 物:《Chinese Journal of Chemical Physics》 (化学物理学报(英文))
年 卷 期:2010年第23卷第4期
页 面:459-464,I0002页
核心收录:
学科分类:07[理学]
主 题:Ferrite Structural property Magnetic property
摘 要:The structure and crystal phase of the nanocrystalline powders of Ni1-xCdxFe2O4(0≤x≤0.5) mixed ferrite, synthesized by wet chemical co-precipitation method, were characterized by X-ray diffraction. Results showed that the lattice parameter increased with increasing Cd concentration. Microstructure was studied by scanning electron microscopy. TG/DTA studies were carried out on co-precipitated sulphate complexes. These studies revealed the low ferritization temperature (650 ℃) of the ferrite system synthesized by presently adopted route of synthesis and occurrence of simultaneous decomposition and ferritization processes. Further studies by infrared spectroscopy were also conducted. Moreover, magnetic properties of the prepared nanoparticles were studied by magnetization and a.c. susceptibility measurements. The response of prepared Ni1-xCdxFe2O4 mixed ferrites to magnetic field was investigated. Results show that, magnetic susceptibility, Curie temperature, and effective magnetic moment decreased as the Cd content increases.