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SYNTHESIS OF BLOCK COPOLYMERS OF STYRENE AND N-(p-SUBSTITUTED PHENYL) MALEIMIDES BY ANIONIC POLYMERIZATION

SYNTHESIS OF BLOCK COPOLYMERS OF STYRENE AND N-(p-SUBSTITUTED PHENYL) MALEIMIDES BY ANIONIC POLYMERIZATION

作     者:Xu, SJ Qiu, KY 

作者机构:BEIJING UNIVCOLL CHEM & MOL ENGNBEIJING 100871PEOPLES R CHINA 

出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))

年 卷 期:1996年第7卷第4期

页      面:367-370页

核心收录:

学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

摘      要:The block copolymers were synthesized by anionic pohymerization via two steps reaction. First, styrene was initiated by n-butyl lithium, then maleimides were added into the living styrene system to obtain block copolymers. 1H-NMR and FT-IR measurements indicated that block coplymers bad been formed From the esults of thermogravimetric, it could be concluded that the block copolymer had a much better thermal stability than random copolymers predared by radical polymerization. Also the surface hydrophilicities of the two kinds of copolymers were compared.

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