Newπ-conjugated cyanostilbene derivatives:Synthesis,characterization and aggregation-induced emission

作     者：Fang Wang Xue Li Sheng Wang Cheng-Peng Li Huan Dong Xiang Ma Sung-Hoon Kim De-Rong Cao 

作者机构：School of Chemistry and Chemical EngineeringState Key Laboratory of Luminescent Materials and DevicesSouth China University of Technology.Cuangzhou 510641China Key Laboratory of Applied Chemistry and School of Chemistry and Chemical EngineeringDevelopment Center for New Materials Engineering&Technologyin Universities of GuangdongLingnan Normal UniversityZhanjiang 524048China Key Laboratory for Advanced Materials and Institute of Fine ChemicalsEast China University of Science and TechnologyShanghai 200237China Department of Advanced Organic Materials Science and EngineeringKyungpook National UniversityDaegu 702-701Republic of Korea 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2016年第27卷第10期

页      面：1592-1596页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070302[理学-分析化学] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：financially supported by NSFC(Nos.21372194,21476075 and 21272072) the Guangdong Yangfan Talent Plan(2013) the Research Funds of Lingnan Normal University(No.QL1402) 

主　　题：π-Conjugated cyanostilbene derivatives1 4-Dihydropyrro[3 2-b]indoleTetraphenylethyleneAggregation-induced emissionMaterials Studio 

摘      要：Two novel Jr-conjugated cyanostilbene derivatives, FLU-CNPH and TPE-CNPH, were designed aria synthesized by introducing the strong electron donor 1, 4-dihydropyrro[3,2-b]indole and AIE electron donor tetraphenylethylene （TPE） to the （3＇,5＇-bis（trifluoromethyl）-biphenyl-4-yl）-acetonitrile, respec- tively, Both of them were fully characterized and their AIE behaviors were investigated using fluorescence spectroscopy and FE-SEM images. Their optimized structures and frontier molecular orbitals were calculated with the DFT by using Materials Studio 7,0 software to study the relationship between the structure and properties.