Visible-light emission properties of α-TeO_2:Ho^(3+)/Yb^(3+)/Eu^(3+) nanoparticles via both up-and down-conversion modes

作     者：张遥 范国康 胡辉 陈伟龙 白燕 ZHANG Yao;FAN Guokang;HU Hui;CHEN Weilong;BAI Yan

作者机构：Department of ChemistryJinan University 

出 版 物：《Journal of Rare Earths》 (稀土学报（英文版）)

年 卷 期：2016年第34卷第11期

页      面：1069-1076页

核心收录：

学科分类：081702[工学-化学工艺] 07[理学] 070205[理学-凝聚态物理] 08[工学] 0817[工学-化学工程与技术] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0702[理学-物理学] 

基　　金：supported by the National Natural Science Foundation of China(21075053) the"Challenge Cup"Undergraduate Extra-curriculum Academics,Science and Technology Works Competition and Student's Platform for Innovation and Entrepreneurship Training Program(201410559056)in Jinan University 

主　　题：up-conversion down-conversion luminescence α-TeO2 nanoparticles rare earths 

摘      要：In this study,α-TeO2：Ho3＋/Yb3＋,α-TeO2：Eu3＋ andα-TeO2：Ho3＋/Yb3＋/Eu3＋ nanoparticles were prepared via a simple hydrothermal process. The up- and down-conversion properties of the as-prepared nanoparticles were tested at room temperature un-der a near-infrared photo source （980 nm） and UV-vis photo source, *** results indicated thatα-TeO2 NPs were a kind of outstanding host material for both up- and down-conversion luminescence. Theα-TeO2：Ho3＋/Yb3＋nanoparticles showed sharp up-conversion emission at 545 and 660 nm under 980 nm excitation, ascribed to the5S2→5I8 and5F5→5I8（Ho3＋） transitions, and weaker down-conversion emission at 545 nm under 455 nm excitation, ascribed to the5S2→5I8（Ho3＋） transitions. Theα-TeO2：Eu3＋nanoparticles showed strong down-conversion emission at 592 and 615 nm under 395 nm excitation, attributed to the5D0→7F1 and 5D0→7F2 （Eu3＋） transitions. Possessing the advantages of these two luminescent materials, the as-prepared tri-doped samples ofα-TeO2：0.5Ho3＋/10Yb3＋/3Eu3＋ （mol.%）nanoparticles could successfully emit visible light via both up- and down-conversion modes.