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Corrosion behaviors for peak-aged Mg-7Gd-5Y-lNd-0.5Zr alloys with oxide films

Corrosion behaviors for peak-aged Mg-7Gd-5Y-lNd-0.5Zr alloys with oxide films

作     者:Quan-Tong Jiang Kui Zhang Xing-Gang Li Yong-Jun Li Ming-Long Ma Guo-Liang Shi Jia-Wei Yuan 

作者机构:State Key Laboratory for Nonferrous Metals and ProcessGeneral Research Institute for Nonferrous MetalsBeijing 100088China 

出 版 物:《Rare Metals》 (稀有金属(英文版))

年 卷 期:2016年第35卷第10期

页      面:758-762页

核心收录:

学科分类:080503[工学-材料加工工程] 0806[工学-冶金工程] 08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学] 0702[理学-物理学] 

基  金:financially supported by the National Natural Science Foundation of China(No.51204020) the National Basic Research Program of China(Nos.2013CB632202 and 2013CB632205) 

主  题:Mg-7Gd-5Y-1Nd-0.5Zr alloys Peak-aged Oxide film Corrosion behavior 

摘      要:The corrosion behaviors of T5 (225 ℃, 6.5 h) and T6 (460 ℃, 2 h + 225 ℃, 12 h) peak-aged Mg-7Gd- 5Y-1Nd-0.5Zr alloys with oxide films were investigated by optical microscope (OM), scanning electron microscopy (SEM), and energy-dispersive spectroscopy (EDS). The weight loss rates and electrochemical tests were also analyzed. The thicknesses of T5 and T6 oxide films are roughly 0.6 and 1.0 μm, respectively. The components of oxide films mainly consist of O, Mg, Y, Nd, and Gd, and the T6 oxide film results in surfaces with larger peaks than T5 oxide film. In addition, Y, Nd, and Gd peaks are all higher than those of Mg-7Gd-5Y- 1Nd-0.5Zr alloys, but Mg peak is consistently far below than that of the alloys. The specimens could be arranged in de- creasing order of corrosion rates and corrosion current densi- ties: T6 oxide film 〈 T5 oxide film 〈 T6 without oxide film 〈 T5 without oxide film. The oxide films are compact to increase the corrosion resistance for Mg-7Gd-5Y-1Nd-0.5Zr alloys, which will provide a guiding insight into the corrosion and protection of Mg-RE alloys in atmospheric environments.

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