Studies on the structural rule of boranes
Studies on the structural rule of boranes作者机构:Institute of Theoretical Chemistry Jilin University Changchun Department of Chemistry Peking University Beijing
出 版 物:《Chinese Journal of Chemistry》 (中国化学(英文版))
年 卷 期:1984年第2卷第1期
页 面:30-36页
主 题:Studies on the structural rule of boranes BMO
摘 要:The authors discuss the structural rule of different kinds of polyhedral boranes andpropose a general topological formula for calculating the number of bonding molecular *** case of single polyhedral boranes,results obtained from the formula are the same as those fromthe famous Wade ***,the formula can also be used to calculate the number of bondingmolecular orbitals of joined-type polyhedral *** have also made some quantum chemistrycalculations to verify the concept that the number of bonding molecular orbitals of boranes can bedetermined by considering only the corresponding boron polyhedral frameworks.