SYNTHESES OF ORGANO-TIN COMPOUNDS THROUGN CARBENE REACTIONS

作     者：曾昭抡 卓仁禧 马纯俊 TSENG CHAO-LUN ZHUO REN-XI,AND MA SHIUN-TSUN Department of Chemistry, Wuhan University Present address: East China Institute of Chemical Technology, Shanghai.

作者机构：Department of Chemistry Wuhan University East China Institute of Chemical Technology Shanghai. 

出 版 物：《Chinese Science Bulletin》 (科学通报(英文版))

年 卷 期：1966年第24卷第2期

页      面：71-页

学科分类：07[理学] 0703[理学-化学] 

主　　题：insertion bonds yielding residue filtering hydride distilled removing dichloro stirring 

摘      要：In a previous paper, insertion of dichlorocarbene into the Sn—Cl bond was reported. In this paper, it is shown that, similar to the Si—H and Ge—H bonds,the Sn—H bond can also undergo insertion reaction with dichlorocarbene: R3SnH+:CCl2→R3SnCl2H （R=C2H5, n-C4H9） Besides, tri-n-butylallyltin undergoes