THE ^(31)P AND ^(13)C NMR STUDIES OF CYCLOPENTYL PHOSPHINE COMPLEXES OF PLATINUM (Ⅱ) AND PALLADIUM (Ⅱ)

作     者：杨振云 韩秀文 李同信 宋永瑞 YANG ZHENYUN HAN XIUWEN LI TONGXIN SONG YONGRUI(Dalian Institute of Chemical Physics, Academia Sinica)

作者机构：Dalian Institute of Chemical Physics Academia Sinica 

出 版 物：《Chinese Science Bulletin》 (Science Bulletin)

年 卷 期：1985年第30卷第11期

页      面：1490-1494页

学科分类：07[理学] 0703[理学-化学] 

主　　题：palladium isomers platinum complexes planar AND PALLADIUM P AND THE Nuclear benzene 

摘      要：Most of phosphine halogen complexes of transition metals, platinum and palladium, possess catalytic properties. The configurations of Pt(Ⅱ) and Pd(Ⅱ) complexes are square planar, existing as cis and trans isomers. Nuclear magnetic resonance studies of the structures of phosphine complexes of platinum and palladium were reported, but no paper appeared on cyclopentyl phosphine except the ear-