菲和芴在等摩尔双表面活性剂/常规表面活性剂混合物中的溶解性(英文)

作     者：Huma Siddiqui Mohammad Kamil Manorama Panda Kabir-ud-Din 

作者机构：Department of Petroleum StudiesAligarh Muslim University Department of ChemistryAligarh Muslim University 

出 版 物：《Chinese Journal of Chemical Engineering》 (中国化学工程学报（英文版）)

年 卷 期：2014年第22卷第9期

页      面：1009-1015页

核心收录：

学科分类：0710[理学-生物学] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 081702[工学-化学工艺] 081704[工学-应用化学] 07[理学] 0817[工学-化学工程与技术] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0703[理学-化学] 

主　　题：表面活性剂 增溶作用 摩尔 双子 十六烷基三甲基溴化铵 混合物 临界胶束浓度 十二烷基硫酸钠 

摘      要：This study deals with the enhanced solubilization of polycyclic aromatic hydrocarbons(PAHs) such as phenanthrene(PHE) and fluorene(FLR) in a pure cationic gemini(G6) and three conventional surfactants [polyethylene glycol dodecyl ether(Brij35), cetyltrimethyl ammonium bromide(CTAB) and sodium lauryl sulfate(SDS)] as well as in their equimolar binary combinations(G6-Brij35, G6-CTAB and G6-SDS). Their solubilization efficiency toward PHE and FLR has been quantified in terms of the molar solubilization ratio(MSR) and the micelle–water partition coefficient(Km). The ideality/nonideality of the mixed micelles is discussed with the help of Clint,Rubingh and Rosen s approaches. These theories determine the deviation of experimental critical micelle concentration(CMC) values from ideal critical micelle concentration, which was measured by evaluating the interaction parameters(βmand βσ). Negative values of βmwere observed in all the equimolar binary systems, which show synergism in the mixed micelles. Whereas at air/liquid interface synergism was observed in the systems G6-CTAB and G6-Brij35; G6-SDS exhibited an antagonistic effect. The order of MSR and Kmwas G6-CTAB N G6-Brij35 N G6-SDS for phenanthrene as well as for fluorene.