CRYSTAL STRUCTURE OF （Et4N）2 [Mo3 （μ3-O） （μ3-Cl） （μ-Cl）3 Cl6]·EtOH

作     者：Shang Maoyu Huang Jinling and Lu JiaxiFujian Institute of Research on the Structure of Matter, Academia Sinica 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学)

年 卷 期：1984年第1期

页      面：13-16页

主　　题：Mo3 Et4N)2 CRYSTAL STRUCTURE OF Cl6 EtOH 

摘      要：Mr=963.9, monoclinic, P21/c, a=11.379(3), b=20.766(2), c=14.487(3) A,β=91.49(2)°, V=3518.9A3, Z=4, Dm=1.81, Dx=1.819 g·cm-3, MoKα radiation, λ=0.71073A, μ=18.167, F(000)=1916, T=293 K, R=0.040 for 3261 reflections. The structure consists of two sets of tetraethylammonium cations and trinuclear Mo cluster anions. The cluster skeleton is formed by three Mo atoms arranged in an isosceles triangle with a Cl and an O atoms as capping ligands.