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Catalytic synthesis of lithium hydride under mild conditions

Catalytic synthesis of lithium hydride under mild conditions

作     者:LIAO Shih-Tsien KONG Wei LIU He-Zhong LI Jing-Kui XU Yun Dalian Institute of Chemical Physics,Academia Sinica,Dalian 

作者机构:Dalian Institute of Chemical Physics Academia Sinica Dalian 

出 版 物:《Chinese Journal of Chemistry》 (中国化学(英文版))

年 卷 期:1985年第3卷第3期

页      面:201-209页

学科分类:07[理学] 0703[理学-化学] 

主  题:Catalytic synthesis of lithium hydride under mild conditions THF 

摘      要:A catalyst composed of titanium tetrachloride and naphthalene or its methyl derivativeswith very high activity was found for the synthesis of *** lithium can be quantitatively hydrogenated to lithium hydride at 25-50℃ under at-mospheric pressure within 2-5 h according to various catalyst *** catalyst stabilitywas investigated and the relationship between catalyst compositions and reaction controlling stepwas established also.

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