STRUCTURE OF DIAQUA（DEMETHYLCANTHARATE）ZINC（II） Zn（C8H8O5）·2H20

作     者：Wang Honghui Zhu Naijue and Fu HengInstitute of Chemistry, Academia Sinica, BeijingLi Rongchang and Wang KuiDepartment of Pharmacy, Beijing. Medical College Wang Honghui Zhu Naijue and Fu HengInstitute of Chemistry, Academia Sinica, BeijingLi Rongchang and Wang KuiDepartment of Pharmacy, Beijing. Medical College

出 版 物：《结构化学》 (Chinese Journal of Structural Chemistry)

年 卷 期：1984年第2期

页      面：87-90页

学科分类：07[理学] 0703[理学-化学] 

主　　题：Zn STRUCTURE OF DIAQUA DEMETHYLCANTHARATE)ZINC C8H8O5 II 

摘      要：Mr=258.57, Monoclinic, P21/a, a=10.907(5), b=8.502(3) ,c=11.083(4) A, β=107.15(3)°, V=982.09A3, Z=4, Dx=1.729 Mgm-3, λ(MoKα)=0.71069A, μ=26.74 cm-1, F(000)=583.90, T=293K. The final R=0.0406 for 1587 unique observed reflections. The demethylcantharate ion acts as a tridentate ligand towards Zn(II) and a monodentate ligand towards another. The oxygen atoms in one carboxylate group bind with two different Zn(II) to form a chain-structure. There are four different types of oxygen coordinating with Zn(II).