Studies on Nucleophilic Ring-Opning Reaction of Ethylene Epoxide by (μ - CH,S )(μ-IMIgS ) Fea (CO)a——Syntheais and Crystal Structure of (μ-Methylthio)- (μ- R -Hydroxylethylthio)hexacarbonyldiiron

作     者：Song Licheng, Wang Ruji, Hu Qingmei and Wang Honggen(Department of Chemistry and Testing Center, Nankai University,Tianjin) Song Licheng, Wang Ruji, Hu Qingmei and Wang Honggen(Department of Chemistry and Testing Center, Nankai University,Tianjin)

出 版 物：《Chemical Journal of Chinese Universities》 (高等学校化学学报(英文版))

年 卷 期：1988年第1期

页      面：38-44页

学科分类：07[理学] 0703[理学-化学] 

主　　题：Syntheais and Crystal Structure of Methylthio CH,S CO)a Fea IMIgS Studies on Nucleophilic Ring-Opning Reaction of Ethylene Epoxide by 

摘      要：A new type of Fe-S complex (C), (μ -CH3S) (μ-HOCH2CH2S) Fe2(CO)6which contains μ-β-hydroxyethyl, has been synthesized in high yield through ring-opening reaction of ethylene epoxide under uncleophilic attack of active complex (A), (μ-CH3S)(μ-IMgS) Fe2(CO)6, followed byan alcoholysis of the intermediate (B). The crystal structure of (C)was determined by an X-ray diffraction technique. The crystal belongs to monoclinic system with space group of C2/c. Cell parameters a= 15.784(3), b = 22.172(3), c=9.774(2)A, β=119.53(2)°, V=2976.3A. Dc = *** cm-3 , Z=8, F(000)=1616 and final R=0.077.