Nitrogen-doped flower-like porous carbon materials directed by in situ hydrolysed MgO： Promising support for Ru nanoparticles in catalytic hydrogenations

作     者：Mingming Li MinghuiTang Jiang Deng Yong Wang 

作者机构：Advanced Materials and Catalysis Group ZJU-NHU United R&D Center Department of Chemistry Zhejiang University Hangzhou310028 China 

出 版 物：《Nano Research》 (纳米研究（英文版）)

年 卷 期：2016年第9卷第10期

页      面：3129-3140页

核心收录：

学科分类：081702[工学-化学工艺] 07[理学] 070205[理学-凝聚态物理] 08[工学] 0817[工学-化学工程与技术] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0702[理学-物理学] 

基　　金：Financial support from the National Natural Science Foundation of China (Nos. 91534114 and 21376208)  the Zhejiang Provincial Natural Science Foundation for Distinguished Young Scholars of China (No. LR13B030001)  the Fundamental Research Funds for the Central Universities  the Program for Zhejiang Leading Team of S&T Innovation  the Partner Group Program of the Zhejiang University  and the Max- Planck Society is greatly appreciated 

主　　题：nitrogen-doped porous carbon MgO in situ hydrolysis ruthenium aromatic hydrogenation 

摘      要：The development of novel simple, and convenient techniques for the fabrication of porous carbon materials with desirable properties, such as tunable pore structures and the presence of nitrogen functionalities, from renewable and abundant biomasses is required. We herein describe an in situ directing method for the preparation of a nitrogen-doped flower-like porous carbon （NFPC） employing arbitrarily shaped MgO from bio-derived glucosamine chloride （GAH）. Experimental evidence demonstrated that the structure directing effect of the Mg（OH）2 nanosheets formed in situ from MgO hydrolysis was key to this process, with the original MgO morphology being irrelevant. Furthermore, this method was applicable for a wide variety of biomass-derived carbon precursors. The resulting NFPC exhibited a high nitrogen content of 〈9 wt.%, and was employed as a support to anchor small Ru nanoparticles （average size = 2.7 nm）. The resulting Ru/NFPC was highly active in heterogeneous hydrogenations of toluene and benzoic acid, which demonstrated the advantages of nitrogen doping in terms of boosting catalytic performance.