Nitration-Oximization of Styrene Derivatives with tert-Butyl Nitrite＂ Synthesis of a-Nitrooximes

作     者：Napasawan Chumnanvej Praewpan Katrun Manat Pohmakotr Vichai Reutrakul Darunee Soorukram Chutima Kuhakarn 

作者机构：Department of Chemistry and Center of Excellence for Innovation in Chemistry (PERCH-CIC) Faculty of Science Mahidol University Rama VI Road Bangkok 10400 Thailand 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2016年第34卷第8期

页      面：830-838页

核心收录：

学科分类：07[理学] 

基　　金：the Thailand Research Fund the Center of Excellence for Innovation in Chemistry (PERCH-CIC) the Office of the Higher Education Commission, Mahidol University under the National Research Universities Initiative the Swedish Research Council through Swedish Research Links Programme in collaboration with Professor Pher G. Andersson, Stockholm University, Sweden CNRS-PICS Program through the collaboration with Professor Fabien Gagosz, Ecole Polytecnique, France for financial support 

主　　题：α‐nitrooximes tert‐butyl nitrite nitration‐oximization styrenes 

摘      要：A highly efficient method for direct nitration‐oximization of styrene derivatives using tert ‐butyl nitrite ( t ‐BuONO) in DMSO was developed. The present method offers a convenient and practical approach for the synthesis of α ‐nitrooximes in moderate to high yields. The salient features entail mild reaction conditions, metal‐free reagent, environmentally benign solvent and simple experimental procedure.