Stereoselective Addition of N-Alkylhydroxylamines to α,β-Unsaturated Nitro Compounds
Stereoselective Addition of N-Alkylhydroxylamines to α,β-Unsaturated Nitro Compounds作者机构：School of Chemical Engineering and Technology Tianjin University Tianjin 300072 Medical College Chinese People＇s Armed Police Force Tianjin 300071
出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)
年 卷 期：2006年第17卷第7期
页 面：859-862页
核心收录：
学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
主 题：N-Alkylhydroxylamines O-alkylhydroxylamines concerted addition mechanism α,β-unsaturated nitro compounds stereoselectivity.
摘 要：N-Alkylhydroxylamines have been shown to undergo a stereospecific cis addition to 1-phenyl-2 -nitropropene compounds, whereas the corresponding O-alkylhydroxylamines give no diastereoselectivity. The concerted addition mechanism was provided to explain the difference.
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