Chemoselective hydrogenation of α,β-unsaturated aldehydes with modified Pd/C catalyst

作     者：Wen Qiang Du Ze Ming Rong Yan Liang Yong Wang Xin Yi Lu Yi Fan Wang Lian Hai Lu 

作者机构：State Key Laboratory of Fine ChemicalsSchool of Chemical EngineeringDalian University of TechnologyDalian 116024China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2012年第23卷第7期

页      面：773-776页

核心收录：

学科分类：081702[工学-化学工艺] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基　　金：supported by the National High Technology Research and Development Program of China(863 Project)(No.2007AA03Z345) the Scientific Research Project for Institute of Higher Education of Education Bureau,Liaoning(No.LT2010021) the Fundamental Research Funds for Dalian University of Technology(No.DUT10RC(3)107) 

主　　题：Pd/C catalyst α,β-Unsaturatcd aldehydes Hydrogenation Selectivity 

摘      要：Selective hydrogenation of α, β-unsaturated aldehydes with modified Pd/C catalyst was *** reduction of C=O bond could be efficiently inhibited by the addition of carbonates,and high selectivity to the corresponding saturated aldehydes was achieved under mild *** protocol provides an alternative for efficient preparation of saturated aldehydes.