Oxidation of n-Butanol and 2-Pentanol with Molecular Oxygen in Supercritical CO2

作     者：Yan Hong CHANG, Tao JIANG, Liang GAO, Quo Ying ZHAO, Hai Xiang GAO, Zhong Hao LI, Jun Chun LI, Zhi Min Liu, Bu Xing HANCenter for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences,Beijing 100080 

作者机构：Center for Molecular Sciences Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2003年第14卷第10期

页      面：1070-1072页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：supported by National Natural Science Foundation of China(20073056) 

主　　题：Oxidation,n-butanol 2-pentanol supercritical CO2 co-solvent. 

摘      要：Oxidation of n-butanol and 2-pentanol using molecular oxygen in supercritical (SC) CO2 with and without co-solvent is investigated. The results showed that the reaction selectivity is high when the reaction is carried out in SC CO2. It has been observed that co-solvent affects conversion and selectivity of the reaction considerably.