Improved Electrochemical Synthesis of Nitro-substituted 1-Aryl-2-pyrrolidinecarbonitriles
Improved Electrochemical Synthesis of Nitro-substituted 1-Aryl-2-pyrrolidinecarbonitriles作者机构:The Key Laboratory for Bioorganic Phosphorus Chemistry & Chemical Biology Ministry of Education Department of Chemistry Tsinghua University Beijing 100084 Department of Chemistry Tsinghua UniversityBeijing 100084 Beijing TH-UNIS Insight Co.Ltd. Beijing 100084
出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))
年 卷 期:2006年第17卷第6期
页 面:736-738页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金:The authors would like to thank the financial support of Beijing TH-UNIS-Insight Co.Ltd.and the National Natural Science Foundation of China (No.20132020) the Ministry of Science and Technology, the Chinese Ministry of Education and Tsinghua University
主 题:Anodic cyanation nitrile pyrrolidine electrochemistry.
摘 要:In this paper, we described an improved electrochemical method for synthesis of some 1-aryl-2-pyrrolidinecarbonitrile derivatives bearing an electron-withdrawing group (NO2). The electrochemical synthesis of titile compounds has been successfully performed in an undivided cell in reasonable yields.