Two highly porous single-crystalline zirconium-based metal-organic frameworks

作     者：Wen-Yang Gao Timmy Thiounn Lukasz Wojtas Yu-Sheng Chen Shengqian Ma 

作者机构：Department of Chemistry University of South Florida Florida 33620 USA ChemMatCARS Center for Advanced Radiation Sources University of Chicago Illinois 60439 USA 

出 版 物：《Science China Chemistry》 (中国科学（化学英文版）)

年 卷 期：2016年第59卷第8期

页      面：980-983页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：supported by the National Science Foundation (DMR-1352065) the University of South Florida ChemMatCARS Sector 15 is supported by the National Science Foundation (NSF/CHE-1346572) 

主　　题：metal-organic frameworks zirconium cluster single-crystalline 

摘      要：Herein we report two highly porous Zr-based metal-organic frameworks （MOFs, 1 and 2） constructed by the truncated octahedral secondary building unit （SBU） of Zr604（OH）4（CO2）12 and the organic linear ligand of 4,4＇-stilbenedicarboxylic acid （H2sbdc） or 4,4＇-azobenezenedicarboxylic acid （H2abdc）. Both Zr-based MOFs are obtained as single crystals of suitable size for single-crystal X-ray diffraction analysis. Furthermore, these two Zr-based MOFs have been fully characterized by powder X-ray diffraction （PXRD） studies, thermogravimetric analysis （TGA）, infrared spectroscopy （IR） and gas adsorption analysis. In particular, their CO2 gas adsorption behaviors have been investigated and discussed.