Facile Synthesis of Phosphorus N-Fluoroalkanesulfonyl Amidines by Cu-catalyzed One-pot Three-component Reaction

作     者：张振华 熊婉婷 顾继伟 朱士正 

作者机构：Key Laboratory of Organofluorine Chemistry Shanghai Institute of Organic Chemistry Chinese Academy of Sciences 345 Lingling Road Shanghai 200032 China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2011年第29卷第12期

页      面：2675-2680页

核心收录：

学科分类：1007[医学-药学(可授医学、理学学位)] 081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 10[医学] 

基　　金：Project supported by the National Natural Science Foundation of China (Nos. 21032006  20972178) and Shanghai Natural Science Council 

主　　题：fluoroalkanesulfonyl azide iminophosphorane alkyne three-component reaction amidine 

摘      要：In the presence of Cu（I） and triethyl amine, one-pot three-component reaction of fluoroalkanesulfonyl azides, alkynes and iminophosphoranes in CH2Cl2 at room temperature gave a novel class of fluorinated phosphorus amidines in good yields.