^(99)Ru and ^(13)C-NMR Spectra for the Tris Chelates of 5-Substituted 1,10-Phenanthrolines with Ruthenium (Ⅱ)
^(99)Ru and ^(13)C-NMR Spectra for the Tris Chelates of 5-Substituted 1,10- Phenanthrolines with Ruthenium (II)作者机构:Department of Chemistry Hunan Normal University Changsha 410081 China Department of Chemistry Nara University of Education Nara 630 Japan
出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))
年 卷 期:1998年第9卷第8期
页 面:765-766页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学]
主 题:NMR spectrum ruthenium(Ⅱ) complex substituent effect
摘 要:13C and 99Ru-NMR chendcal shifts are reported for the ruthenium(II) tris complexes of5-substitUted 1,10-phenanthrolines. It has been found that both of them are affected by the substituents on the phenanthrolines in a direction consistent with that expected from the electron withdrawing ability of the substituent.