Synthesis and Crystal Structure of Complex {[Cu（N-men）2（cda）2]·[Cu（N-men）2]·（ClO4）2}（N-men=N-Methylethylenediamine,cda=Carbamyldicyanomethanide Anion）

作     者：SHI Jing-Min XU Wen LU Su-QiaoWU Chang-Ju GE Jie-Chao ZHANG Zhi-De(Department of Chemistry, Shandong Normal University, Jinan 250014, China)(Department of Chemistry, Taiyuan Education Institute, Taiyuan 030001, China) 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学(英文版))

年 卷 期：2002年第6期

页      面：640-642页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：This work was supported by the Natural Science Foundation of Shandong province as the key project(No.Z99B02) general project(No.Q98B02118) 

主　　题：synthesis crystal structure copper complex 

摘      要：Mononuclear complex {[Cu(N-men)2(cda)2]·[Cu(N-men)2]-(ClO4)2} was synthesized by sodium carbamyldicyanomethanide Na(cda), N-methylethylenediamine and hydrate copper perchlorate. The crystal belongs to the triclinic system, space group P 1 with a = 7.229(2), b = 8.114(2), c = 15.936(4) A, α = 80.511(4), β = 78.993(4), r= 72.118(4)°, V = 867.6(3) A3, Z = 1, C20H44Cl2Cu2N14O10, Mr = 838.68, Dc = 1.605 g/cm3, F(000) = 434 and μ = 1.449 mm-1. The structure was refined to R = 0.0480 and wR = 0.1289 for 2503 observed reflections (I 2σ(I)). In the complex there exist two kinds of coordination models for Cu (II) ions. One is that the Cu (II) ion is coordinated by four nitrogen atoms which are from two N-men molecules, and a slightly distorted square planar coordinate environment is formed around the Cu (II) ion; the other is that the Cu (II) ion is coordinated by six nitrogen atoms, of which four are from two N-men molecules and the left from nitrile groups, resulting in a distorted octahedron around the