新型含葡萄糖基手性Salen配体及其Mn^(3+)、Fe^(3+)、Co^(2+)、Cu^(2+)配合物的合成与表征
Synthesis and Characterization of a Novel Chiral Salen Ligand with a Glucose Moiety and Its Mn(Ⅲ), Fe(Ⅲ), Co(Ⅱ) and Cu(Ⅱ) Complexes作者机构:河北工业大学化工学院天津300130
出 版 物:《无机化学学报》 (Chinese Journal of Inorganic Chemistry)
年 卷 期:2006年第22卷第6期
页 面:1133-1136页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学]
主 题:葡萄糖衍生物 手性金属配合物 Salen配体 Schiff碱 环己二胺
摘 要:A novel chiral Salen ligand with a glucose moiety was synthesized from the condensation of 1,2:5,6-di-O-isopropylidene-3-O-methylene-5-(3-tert-butyl-2-hydroxy benzaldehyde) -α-D-glucofuranose with (1R,2R)-1,2-diaminocyclohexane. Several chiral complexes of Mn3+, Fe3+, Co2+ and Cu2+ were prepared from this ligand. Both the ligand and the complexes were characterized by elemental analysis, NMR, IR, MS, and UV-Vis.