Two Zinc Architectures:A Mononuclear Complex and a 2D Wave-like Organic-inorganic Hybrid Layer

作     者：靳梅芳 戴昉纳 孙道峰 

作者机构：Key Lab for Colloid and Interface Chemistry of Education MinistryDepartment of ChemistryShandong University 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学（英文）)

年 卷 期：2010年第29卷第12期

页      面：1834-1840页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：Supported by the NNSFC (20701025) the NSF of Shandong Province (Y2008B01),and Shandong University 

主　　题：supramolecular architecture zinc metal-organic framework mixed organic ligands supramolecular interactions 

摘      要：Self-assembly of Zn（NO3）2·6H2O and 2,3,5,6-tetrabromoterephthalic acid（H2TBTA） gave rise to two new zinc metal-organic frameworks,Zn（HTBTA）2（phen）2·H2O（1） and Zn（TBTA）1/2（μ2-OH）（H2O）·0.25EtOH（2）.Complex 1 is a mononuclear *** hydrogen bonding interactions further connect the mononuclear molecules to generate a 2D supramolecular *** 2 is a 2D organic-inorganic hybrid layer framework constructed from 1D rod-shaped secondary building units.