Syntheses,Crystal Structures and Complexing Properties of 1,3-Distal Calix[4]arene Schiff Bases

作     者：LI Liang GU Wei-wei YAN Chao-guo 

作者机构：College of Chemistry ＆ Chemical Engineering Yangzhou University Yangzhou 225002 P R. China 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：2010年第26卷第1期

页      面：38-45页

核心收录：

学科分类：082803[工学-农业生物环境与能源工程] 081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0828[工学-农业工程] 0804[工学-仪器科学与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：Supported by the National Natural Science Foundation of China(No.20672091) 

主　　题：Calixarene Schiffbase Crystal structure Metal complex UV spectroscopy 

摘      要：Novel 1,3-distal p-tert-butylcalix[4]arene Schiff bases were efficiently synthesized in three steps. At first p-tert-hutylcalix[4]arene was reacted with N-2-hydroxyethylphthalimide catalyzed by TPP/DEAD or alkylated with ω-hatoalkylphthalimide in the system of K2CO3/KI/CH3COCH3 to give 1,3-distal diphthalimidoalkyl calixarenes, which were in turn hydrazinolyzed to give diaminoalkyl calixarenes. Then with the aid of the condensation of active calixarene amines with salicylaldehyde, 2-hydroxy-l-naphthaldehyde or pyridine-2-carboxaldehyde, a series of 1,3-distal calixarene Schiff bases was prepared in satisfied yields. The single crystal structures and complexing properties of these Schiff bases for transition metal ions were studied.