Crystal Structure of Bis｛1-(2-methoxyethyl)indenyl｝dysprosium Chloride

作     者：XIE Mei Hua ② HAO Xue Shi MA Huai Zhu (Institute of Organic Chemistry, Anhui Normal University, Wuhu Anhui 241000) WU Qiang Jin HUANG Zi Xiang (Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, 

作者机构：安徽师范大学 安徽 芜湖 2 41 0 0 0 中科院福建物质结构所 福建 福州 350 0 0 2 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学(英文版))

年 卷 期：2000年第19卷第4期

页      面：253-258页

核心收录：

学科分类：07[理学] 070205[理学-凝聚态物理] 08[工学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 0702[理学-物理学] 

基　　金：安徽省重点学科基金 

主　　题：methoxyethyl)indenyl ligand dysprosium crystal structure. 

摘      要：The title complex bis｛1 (2 methoxyethyl)indenyl｝dysprosium chloride ((CH 3OCH 2CH 2C 9H 6) 2DyCl, M r =544.42) crystallizes in the triclinic,space group P 1(No.2) with unit cell parameters a = 10.326(1), b = 10.591(1), c = 20.256(3) , α = 91.543(9), β = 97.69(1), γ = 94.754(9)°, V=2186.2(9)  3, Z = 4, F(000)=1076, D C= 1.65g/cm 3, μ =35.87cm -1, R =0.042 and R w =0.051 for 6193 observed reflections with I3σ(I ). X ray crystal structure study shows there are two crystallographically independent molecules A and B (A=(CH 3OCH 2CH 2C 9H 6) 2 Dy(1) Cl, B=(CH 3OCH 2CH 2C 9H 6) 2Dy(2)Cl) in an asymmetric unit of the title complex. Each molecule was unsolvated monomeric molecule with a trans arrangement of both the sidearms and indenyl rings.