可视化方法研究合成硫醚反应动力学

作     者：胡方锋 陈金芳 徐俊辉 陈中 HU Fangfeng;CHEN Jinfang;XU Junhui;CHEN Zhong

作者机构：武汉工程大学化工与制药学院湖北省新型反应器与绿色化学工艺重点实验室湖北武汉430073 

出 版 物：《化工学报》 (CIESC Journal)

年 卷 期：2007年第58卷第9期

页      面：2249-2254页

核心收录：

学科分类：07[理学] 070304[理学-物理化学(含∶化学物理)] 0703[理学-化学] 

基　　金：国家自然科学基金项目(20276055) 

主　　题：可视化 合成硫醚 浓度-灰度标准曲线 反应动力学 液液相界面 

摘      要：A novel technique combining photoelectronic microscopy and computer imaging tracing was used to investigate the synthesis of thioether(2-[3-methyl-4-(2,2,2-trifluoro-ethoxy)-pyridine-2-(methylsulfanyl)]-1H-benzoimidazole),which is an intermediate for *** in sub-microcosmic surroundings was realized to study interfacial *** reaction kinetics study by a visualization technique was carried out in a mini-reactor,and the concentration-gray scale standard curves for thioether were obtained by analyzing the gray scales of digital *** on the concentration-gray scale standard curves,the reactant concentrations at different times were calculated,and the reaction kinetics curve and reaction rate equation were *** the total mass-transfer resistance from bulk phase to interface of sodium imidazole and bromopyridine was ***-liquid interface of synthesizing thioether was observed and its mass transfer mechanism was discussed.