Surface ligand-promoted heterogeneous CO2 catalysis

作     者：Zhe Lu Lu Wang 

作者机构：School of Science and EngineeringThe Chinese University of Hong Kong 

出 版 物：《Science China Chemistry》 (中国科学:化学(英文版))

年 卷 期：2025年第2期

页      面：444-457页

核心收录：

学科分类：083002[工学-环境工程] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基　　金：supported by the National Key R&D Program of China (2021YFF0502000) the National Natural Science Foundation of China (52102311) the Shenzhen Natural Science Foundation 2022 the Shenzhen Key Laboratory of Eco-materials and Renewable Energy (ZDSYS20200922160400001) the Provincial Talent Plan (2023TB0006) the University Development Fund (UDF01001721) 

摘      要：Heterogeneous CO2catalysis towards the synthesis of high-value products provides a potent pathway for achieving carbon neutrality. The distinctive attributes of surface ligands allow for highly effective tuning of the kinetics and mechanisms to enhance CO2conversion performance. In this review, the catalytic contributions of surface ligands from the view of structure modulation, mechanism modulation, mass transfer, and energy transfer were summarized. The relationships between surface ligands and the performance of functionalized catalysts were further explored. Subsequently, the applications of hydrocarbon chain spacer, hydroxyl and amino as terminal, and SiOxligand in thermal, photo, and photothermal CO2conversion were investigated. By examining the current limitations and advancements, we concluded with insights into potential future research directions that focus on the development of precisely tuned active sites for highly efficient CO2conversion.