Emerging progress:photochemical transformation of nitroso compounds

作     者：Ze-Le Chen Qiang-Qiang Li Armido Studer Jun Xuan 

作者机构：Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized MaterialsSchool of Chemistry&Chemical EngineeringAnhui UniversityHefei 230601China Organisch-Chemisches InstitutUniversitat MünsterMunster 48149Germany 

出 版 物：《Science China Chemistry》 (中国科学(化学英文版))

年 卷 期：2025年第68卷第1期

页      面：118-133页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：supported by the National Natural Science Foundation of China(22301292,21971001) the Distinguished Young Research Project of Anhui Higher Education Institution(2023AH020003) Armido Studer thanks the Deutsche Forschungsgemeinschaft(DFG)for funding(STU 280/92-1) 

主　　题：nitroso compounds photochemistry radical reaction carbene transformation nitrosoarenes 

摘      要：Nitroso compounds have emerged as highly valuable reaction partners or reagents in organic synthesis due to their rich *** versatile profile of these compounds allows them to function as electrophiles,nucleophiles,diradicals,and radical acceptors in diverse *** recent years,notable progress has been made in harnessing photochemical reactions with nitroso compounds to prepare N,O-containing structures using mild and eco-friendly *** nitroso compounds like nitrosoarenes,acyloxy nitroso compounds,N-nitrosoamines and nitrites have received significant attention for their ability to introduce NO moieties into complex molecules that are otherwise difficult to *** this review,we provide an overview of the recent advancements in the visible light-induced conversion of nitroso compounds,with particular emphasis on their role as bifunctional reagents and acceptors of radicals,carbenes and nitrenes.