SYNTHESIS AND CHARACTERIZATION OF A NOVEL REACTIVE LADDER-LIKE POLYSILSESQUIOXANE WITH LATERAL BROMOPHENYL GROUPS

作     者：张榕本 

作者机构：PCLCC State Key Lab of Polymer Physics and Chemistry Center for Molecular Science Institute of ChemistryChinese Academy of Sciences Beijing 100080 China 

出 版 物：《Chinese Journal of Polymer Science》 (高分子科学（英文版）)

年 卷 期：2004年第22卷第5期

页      面：445-451页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：This work was supported by the National Natural Science Foundation of China (No. 20174047  20204016  50273043) andDow Corning Corporation  USA 

主　　题：Ladder-like Polysilsesquioxane Stepwise coupling polymerization Hydrosilylation 

摘      要：A novel soluble, reactive ladder-like polysilsesquioxane (L) with lateral bromophenyl groups was synthesized successfully by stepwise coupling polymerization (SCP) method including preaminolysis, hydrolysis and polycondensation steps. The monomer 3-trichlorosilylpropoxy-4-bromobenzene (M) was first prepared via hydrosilylation reaction catalyzed by dicyclopentadienylplatinum dichloride (Cp2PtCl2). The title polymer (L) was characterized by 1H-NMR, 29Si-NMR, FTIR, X-ray diffraction (XRD), DSC and vapor pressure osmometry (VPO). The experimental results indicate that the polymer (L) possesses a typical ladder-like structure.