Synthesis and Characterization of a Novel Grid Coordination Polymer Network Generated from Unsymmetrically Bridging Ligand

作     者：弓亚琼 贾宏云 张树海 

作者机构：Chemical Industry and Ecology InstituteNorth University of China 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学（英文）)

年 卷 期：2015年第34卷第12期

页      面：1857-1861页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：Supported by Shanxi Scholarship Council of China and Technology Foundation for Selected Overseas Chinese Scholar of Shanxi 

主　　题：silver(I) flexible crystal structure 

摘      要：Self-assembly of pyta （pyta = N-（4-pyridylmethyl） triazole） with Ag（I） center by layer-separating diffusion method at ambient temperature gives rise to a new supramolecular [Ag（p-pyta）CIO4]n which has been characterized by single-crystal X-ray diffraction. The polymer crystallizes in a hexagonal space group R-3 with a = 22.456（7）, b = 22.456（7）, c = 14.570（1） A, V= 6363（6） A3, Z = 4, C36H36Ag4.5C14.5N18O18, Mr = 1653.77, Dc = 1.726 g/cm3, F（000） = 3240, μ（MoKa） = 1.625 mm^-1, the final R = 0.0449 and wR = 0.1397 for 2744 observed reflections with I〉2σ（I）.