咨询与建议

看过本文的还看了

相关文献

该作者的其他文献

文献详情 >Hydrolysis of Phosphorodithioa... 收藏

Hydrolysis of Phosphorodithioates with a Seven-membered Ring( Ⅰ )——Kinetics and Mechanism of Acidic Hydrolysis

Hydrolysis of Phosphorodithioates with a Seven-membered Ring( Ⅰ )——Kinetics and Mechanism of Acidic Hydrolysis

作     者:Zhong Diyuan, Guo Hongyou, Ren Xingang, Cao Weiliang, Xue Shilei and Wang Zouxin (Department of Applied Chemistry, Beijing Institute of Chemical Technology, Beijing) 

出 版 物:《Chemical Research in Chinese Universities》 (高等学校化学研究(英文版))

年 卷 期:1991年第7卷第3期

页      面:188-192页

核心收录:

学科分类:07[理学] 0703[理学-化学] 

基  金:Supported by the National Natural Science Foundation of China 

主  题:Kinetics Mechanism Acidic hydrolysis Phosphorodithioates 

摘      要:Introduction The phosphorodithioate is an important organophosphate pesticide. The hydrolysis reactions are very important to the metabolism of the pesticides. There have been many papers published in this domain concerning the hydrolysis of organophosphate esters. Studies on the hydrolysis of phosphorodithioate esters with a seven-membered ring, however, have rarely been reported. O, O-biphenyl S-alkyl phosphorothiolothionates with notable biological activities have recently been synthesized. In the present pater, UV spectroscopic method and molecular orbital calculation are used to carry out a research into the kinetics and-mechanisms of their hydrolyses.

读者评论 与其他读者分享你的观点

用户名:未登录
我的评分